TY - JOUR
T1 - 1,1-Dimethylhydrazidogallane and a gallium hydrazide with two Ga2N2 rings bridged by two NNMe2 ligands
AU - Luo, Bing
AU - Gladfelter, Wayne L.
PY - 2000/5/21
Y1 - 2000/5/21
N2 - Volatile, thermally robust 1,1-dimethylhydrazidogallane, [H2GaN(H)NMe2]2 1 has been synthesized from the reaction of H3Ga(NMe3) with H2NNMe2, whereas reaction of compound 1 with an excess of H2NNMe2 at elevated temperature afforded a gallium hydrazide derivative, Ga4[N(H)NMe2]8(NNMe2)2 2, which possessed a novel structure of two Ga2N2 rings bridged by NNMe2 groups.
AB - Volatile, thermally robust 1,1-dimethylhydrazidogallane, [H2GaN(H)NMe2]2 1 has been synthesized from the reaction of H3Ga(NMe3) with H2NNMe2, whereas reaction of compound 1 with an excess of H2NNMe2 at elevated temperature afforded a gallium hydrazide derivative, Ga4[N(H)NMe2]8(NNMe2)2 2, which possessed a novel structure of two Ga2N2 rings bridged by NNMe2 groups.
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U2 - 10.1039/b001010n
DO - 10.1039/b001010n
M3 - Article
AN - SCOPUS:0034697491
SN - 1359-7345
SP - 825
EP - 826
JO - Chemical Communications
JF - Chemical Communications
IS - 10
ER -