A concise total synthesis of (±)- and (-)-okilactomycin D

Dawen Niu; Thomas R. Hoye

doi:10.1021/ol203355g

A concise total synthesis of (±)- and (-)-okilactomycin D

Dawen Niu, Thomas R. Hoye

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.

Original language	English (US)
Pages (from-to)	828-831
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	3
DOIs	https://doi.org/10.1021/ol203355g
State	Published - Feb 3 2012

Access

10.1021/ol203355g

OpenUrl availability

Full text

Cite this

@article{144e6c519b8047c789bea8f8a2be8cb5,

title = "A concise total synthesis of (±)- and (-)-okilactomycin D",

abstract = "The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.",

author = "Dawen Niu and Hoye, {Thomas R.}",

year = "2012",

month = feb,

day = "3",

doi = "10.1021/ol203355g",

language = "English (US)",

volume = "14",

pages = "828--831",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - A concise total synthesis of (±)- and (-)-okilactomycin D

AU - Niu, Dawen

AU - Hoye, Thomas R.

PY - 2012/2/3

Y1 - 2012/2/3

N2 - The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.

AB - The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.

UR - http://www.scopus.com/inward/record.url?scp=84856695735&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84856695735&partnerID=8YFLogxK

U2 - 10.1021/ol203355g

DO - 10.1021/ol203355g

M3 - Article

C2 - 22273402

AN - SCOPUS:84856695735

SN - 1523-7060

VL - 14

SP - 828

EP - 831

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

A concise total synthesis of (±)- and (-)-okilactomycin D

Abstract

Access

OpenUrl availability

Other files and links

Fingerprint

Cite this