Abstract
A pushy Lewis base: Previously unobserved non-heme FeIV=O intermediates can be trapped in the decay of FeIIIOOR species by the addition of Lewis bases (represented by the green sphere) that promote O-O bond homolysis (see picture; Fe purple, O red).
Original language | English (US) |
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Pages (from-to) | 3671-3673 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 42 |
Issue number | 31 |
DOIs | |
State | Published - Aug 11 2003 |
Keywords
- High-valent species
- Iron
- Kinetics
- Oxo ligands
- Push effect