A mild transamination route to [EtGaNEt]6: A twelve-vertex gallium-nitrogen cluster

Bing Luo; Wayne L. Gladfelter

doi:10.1023/A:1021107110295

A mild transamination route to [EtGaNEt]₆: A twelve-vertex gallium-nitrogen cluster

Bing Luo, Wayne L. Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The reaction of [EtGa(NMe₂)₂]₂ with neat, excess EtNH₂ afforded a glassy solid whose IR spectrum did not exhibit any N-H absorptions and ¹H NMR spectrum indicated the presence of more than one compound. Refluxing a toluene solution of this solid afforded the imido gallium compound, (EtGaNEt)₆ (1), in 56% yield. Compound 1 crystallize d in space group R3̄ with a hexagonal prismatic structure constructed with two planar Ga₃N₃ rings.

Original language	English (US)
Pages (from-to)	461-467
Number of pages	7
Journal	Journal of Cluster Science
Volume	13
Issue number	4
DOIs	https://doi.org/10.1023/A:1021107110295
State	Published - 2002

Bibliographical note

Funding Information:
The authors gratefully acknowledge support from the National Science Foundation. We also thank Dr. Victor G. Young for his assistance in the single crystal XRD experiment.

Keywords

Amidogallium
Imidogallium
Structure
Transamination

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10.1023/A:1021107110295

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Cite this

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title = "A mild transamination route to [EtGaNEt]6: A twelve-vertex gallium-nitrogen cluster",

abstract = "The reaction of [EtGa(NMe2)2]2 with neat, excess EtNH2 afforded a glassy solid whose IR spectrum did not exhibit any N-H absorptions and 1H NMR spectrum indicated the presence of more than one compound. Refluxing a toluene solution of this solid afforded the imido gallium compound, (EtGaNEt)6 (1), in 56% yield. Compound 1 crystallize d in space group R{\=3} with a hexagonal prismatic structure constructed with two planar Ga3N3 rings.",

keywords = "Amidogallium, Imidogallium, Structure, Transamination",

author = "Bing Luo and Gladfelter, {Wayne L.}",

note = "Funding Information: The authors gratefully acknowledge support from the National Science Foundation. We also thank Dr. Victor G. Young for his assistance in the single crystal XRD experiment.",

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T1 - A mild transamination route to [EtGaNEt]6

T2 - A twelve-vertex gallium-nitrogen cluster

AU - Luo, Bing

AU - Gladfelter, Wayne L.

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PY - 2002

Y1 - 2002

N2 - The reaction of [EtGa(NMe2)2]2 with neat, excess EtNH2 afforded a glassy solid whose IR spectrum did not exhibit any N-H absorptions and 1H NMR spectrum indicated the presence of more than one compound. Refluxing a toluene solution of this solid afforded the imido gallium compound, (EtGaNEt)6 (1), in 56% yield. Compound 1 crystallize d in space group R3̄ with a hexagonal prismatic structure constructed with two planar Ga3N3 rings.

AB - The reaction of [EtGa(NMe2)2]2 with neat, excess EtNH2 afforded a glassy solid whose IR spectrum did not exhibit any N-H absorptions and 1H NMR spectrum indicated the presence of more than one compound. Refluxing a toluene solution of this solid afforded the imido gallium compound, (EtGaNEt)6 (1), in 56% yield. Compound 1 crystallize d in space group R3̄ with a hexagonal prismatic structure constructed with two planar Ga3N3 rings.

KW - Amidogallium

KW - Imidogallium

KW - Structure

KW - Transamination

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