A stable open-shell redox active ditopic ligand

N. M. Bonanno; A. J. Lough; K. E. Prosser; C. J. Walsby; P. K. Poddutoori; M. T. Lemaire

doi:10.1039/c5dt04061b

A stable open-shell redox active ditopic ligand

N. M. Bonanno, A. J. Lough, K. E. Prosser, C. J. Walsby, P. K. Poddutoori, M. T. Lemaire

Chemistry & Biochemistry

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Abstract

Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 × 2] grid-type structures.

Original language	English (US)
Pages (from-to)	5460-5463
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	13
DOIs	https://doi.org/10.1039/c5dt04061b
State	Published - 2016

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© 2016 The Royal Society of Chemistry.

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AU - Bonanno, N. M.

AU - Lough, A. J.

AU - Prosser, K. E.

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AU - Poddutoori, P. K.

AU - Lemaire, M. T.

PY - 2016

Y1 - 2016

N2 - Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 × 2] grid-type structures.

AB - Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 × 2] grid-type structures.

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ER -

A stable open-shell redox active ditopic ligand

Abstract

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