A temperature-dependent kinetics study of the CH3O2 + NO reaction using chemical ionization mass spectrometry

Peter W Villalta; L. Gregory Huey; Carleton J. Howard

doi:10.1021/j100034a023

A temperature-dependent kinetics study of the CH₃O₂ + NO reaction using chemical ionization mass spectrometry

Peter W Villalta, L. Gregory Huey, Carleton J. Howard

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The rate constant of the CH₃O₂ + NO gas-phase reaction was measured over the temperature range 199-429 K using chemical ionization mass spectrometry detection of the CH₃O₂ reactant. The temperature-dependent expression for the rate constant was determined to be k(T) = (2.8 ± 0.5) × 10^-12 exp{(285 ± 60)/T} cm³ molecule^-1 s^-1. The 298 K rate constant, k = (7.5 ± 1.3) × 10^-12 cm³ molecule^-1 s^-1, agrees well with previous results.

Original language	English (US)
Pages (from-to)	12829-12834
Number of pages	6
Journal	Journal of Physical Chemistry
Volume	99
Issue number	34
DOIs	https://doi.org/10.1021/j100034a023
State	Published - Jan 1 1995
Externally published	Yes

Access

10.1021/j100034a023

OpenUrl availability

Full text

Cite this

@article{00c7df2550e24049a8ac760ff81fbfe8,

title = "A temperature-dependent kinetics study of the CH3O2 + NO reaction using chemical ionization mass spectrometry",

abstract = "The rate constant of the CH3O2 + NO gas-phase reaction was measured over the temperature range 199-429 K using chemical ionization mass spectrometry detection of the CH3O2 reactant. The temperature-dependent expression for the rate constant was determined to be k(T) = (2.8 ± 0.5) × 10-12 exp{(285 ± 60)/T} cm3 molecule-1 s-1. The 298 K rate constant, k = (7.5 ± 1.3) × 10-12 cm3 molecule-1 s-1, agrees well with previous results.",

author = "Villalta, {Peter W} and Huey, {L. Gregory} and Howard, {Carleton J.}",

year = "1995",

month = jan,

day = "1",

doi = "10.1021/j100034a023",

language = "English (US)",

volume = "99",

pages = "12829--12834",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "34",

}

TY - JOUR

T1 - A temperature-dependent kinetics study of the CH3O2 + NO reaction using chemical ionization mass spectrometry

AU - Villalta, Peter W

AU - Huey, L. Gregory

AU - Howard, Carleton J.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The rate constant of the CH3O2 + NO gas-phase reaction was measured over the temperature range 199-429 K using chemical ionization mass spectrometry detection of the CH3O2 reactant. The temperature-dependent expression for the rate constant was determined to be k(T) = (2.8 ± 0.5) × 10-12 exp{(285 ± 60)/T} cm3 molecule-1 s-1. The 298 K rate constant, k = (7.5 ± 1.3) × 10-12 cm3 molecule-1 s-1, agrees well with previous results.

AB - The rate constant of the CH3O2 + NO gas-phase reaction was measured over the temperature range 199-429 K using chemical ionization mass spectrometry detection of the CH3O2 reactant. The temperature-dependent expression for the rate constant was determined to be k(T) = (2.8 ± 0.5) × 10-12 exp{(285 ± 60)/T} cm3 molecule-1 s-1. The 298 K rate constant, k = (7.5 ± 1.3) × 10-12 cm3 molecule-1 s-1, agrees well with previous results.

UR - http://www.scopus.com/inward/record.url?scp=0000776563&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000776563&partnerID=8YFLogxK

U2 - 10.1021/j100034a023

DO - 10.1021/j100034a023

M3 - Article

AN - SCOPUS:0000776563

SN - 0022-3654

VL - 99

SP - 12829

EP - 12834

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 34

ER -

A temperature-dependent kinetics study of the CH₃O₂ + NO reaction using chemical ionization mass spectrometry

Abstract

Access

OpenUrl availability

Other files and links

Fingerprint

Cite this