Activation of nitroarenes in the homogenous catalytic carbonylation of nitroaromatics via an oxygen-atom-transfer mechanism induced by inner-sphere electron transfer

Engineering & Materials Science

• Carbonylation 100%
• Atoms 54%
• Electrons 52%
• Chemical activation 47%
• Oxygen 42%
• Ruthenium 26%
• Ethane 22%
• Single crystals 20%
• Enthalpy 17%
• Crystals 17%
• X ray diffraction 17%
• Carbon dioxide 16%
• Thermodynamics 15%
• Entropy 14%

Medicine & Life Sciences

• Carbon Monoxide 53%
• Electrons 42%
• bis(diphenylphosphine)ethane 40%
• Oxygen 37%
• Ruthenium 27%
• Kinetics 25%
• Thermodynamics 21%
• Entropy 21%
• X-Ray Diffraction 21%
• Carbon Dioxide 18%

Chemical Compounds

• Nitroarene 68%
• Carbonylation 59%
• Electron Transfer 36%
• Deoxygenation 13%
• Chloro Group 8%
• 1,2-bis(diphenylphosphino)ethane 7%
• Activation Enthalpy 7%
• Reduction Potential 6%
• Phenyl Group 5%
• Polar Solvent 5%
• Rate-Determining Step 5%
• Kinetics Type 5%
• Methyl Group 4%
• P21 4%
• Entropy 4%
• Carbon Dioxide 4%
• Monoclinic Space Group 4%
• Space Group 4%
• Single Crystal X-Ray Diffraction 4%
• Donor 3%
• Thermodynamics 3%
• Electron Particle 3%