Abstract
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
Original language | English (US) |
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Pages (from-to) | 5687-5690 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 55 |
Issue number | 41 |
DOIs | |
State | Published - Oct 8 2014 |
Bibliographical note
Publisher Copyright:© 2014 Elsevier Ltd. All rights reserved.
Keywords
- Catalytic oxidation
- Oxygenation
- Phthalocyanines
- Tetraazaporphyrin