Construction of the steroid framework via a functionalized macrocyclic compound

Gerald Dyker; Peter Grundt

doi:10.1002/(sici)1099-0690(199901)1999:1<323::aid-ejoc323>3.0.co;2-m

Construction of the steroid framework via a functionalized macrocyclic compound

Gerald Dyker, Peter Grundt

Chemistry & Biochemistry

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16 Scopus citations

Abstract

A palladium-catalyzed intramolecular coupling process leads to a functionalized macrocycle suitable for a double transannular cyclization. The resulting steroid framework, and its stereo- and regioisomers, are identified by analysis of the NMR-spectroscopic data.

Original language	English (US)
Pages (from-to)	323-327
Number of pages	5
Journal	European Journal of Organic Chemistry
Issue number	1
DOIs	https://doi.org/10.1002/(sici)1099-0690(199901)1999:1<323::aid-ejoc323>3.0.co;2-m
State	Published - Jan 1999

Keywords

Heck reaction
Macrocycles
Robinson-type annulation
Steroids

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abstract = "A palladium-catalyzed intramolecular coupling process leads to a functionalized macrocycle suitable for a double transannular cyclization. The resulting steroid framework, and its stereo- and regioisomers, are identified by analysis of the NMR-spectroscopic data.",

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Construction of the steroid framework via a functionalized macrocyclic compound

Abstract

Keywords

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