Development of Imino-λ3-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions

Takafumi Baba; Shunsuke Takahashi; Yui Kambara; Akira Yoshimura; Victor N. Nemykin; Viktor Zhdankin; Akio Saito

doi:10.1002/adsc.201700934

Development of Imino-λ³-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions

Takafumi Baba, Shunsuke Takahashi, Yui Kambara, Akira Yoshimura, Victor N. Nemykin, Viktor Zhdankin, Akio Saito

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Aiming at the enhancement of electrophilicity of imino-λ³-iodanes, we have developed (tosylimino)pentafluorophenyl-λ³-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ³-iodane in the [2+2+1]-type synthesis of imidazoles. (Figure presented.).

Original language	English (US)
Pages (from-to)	3860-3864
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	359
Issue number	21
DOIs	https://doi.org/10.1002/adsc.201700934
State	Published - Nov 10 2017

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

Alkynes
cycloaddition
imidazoles
iminoiodanes
metal-free

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AU - Kambara, Yui

AU - Yoshimura, Akira

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor

AU - Saito, Akio

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