First emission studies of Tc2X82- systems (X = Cl, Br)

Breeze N. Briggs; David R. McMillin; Tanya K. Todorova; Laura Gagliardi; Frederic Poineau; Kenneth R. Czerwinski; Alfred P. Sattelberger

doi:10.1039/c0dt00751j

First emission studies of Tc₂X₈^2- systems (X = Cl, Br)

Breeze N. Briggs, David R. McMillin, Tanya K. Todorova, Laura Gagliardi, Frederic Poineau, Kenneth R. Czerwinski, Alfred P. Sattelberger

Chemistry (Twin Cities)

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11 Scopus citations

Abstract

The emission spectra of the solids [n-Bu₄N]₂Tc ₂X₈ (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the ¹δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

Original language	English (US)
Pages (from-to)	11322-11324
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	47
DOIs	https://doi.org/10.1039/c0dt00751j
State	Published - Dec 21 2010

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abstract = "The emission spectra of the solids [n-Bu4N]2Tc 2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.",

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AU - Briggs, Breeze N.

AU - McMillin, David R.

AU - Todorova, Tanya K.

AU - Gagliardi, Laura

AU - Poineau, Frederic

AU - Czerwinski, Kenneth R.

AU - Sattelberger, Alfred P.

PY - 2010/12/21

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AB - The emission spectra of the solids [n-Bu4N]2Tc 2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

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First emission studies of Tc₂X₈^2- systems (X = Cl, Br)

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