From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4-

Lian Xu Shi; Wen Feng Zhao; Xuan Xu; Jing Tang; Chuan De Wu

doi:10.1021/ic2020572

From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn ₄(H ₂O) ₁₈WZnMn ₂(H ₂O) ₂(ZnW ₉O ₃₄) ₂] ^4-

Lian Xu Shi, Wen Feng Zhao, Xuan Xu, Jing Tang, Chuan De Wu

Center for Drug Design

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A 1D anionic polyoxometalate, [Mn ₄(H ₂O) ₁₈WZnMn ₂(H ₂O) ₂(ZnW ₉O ₃₄) ₂] ^4-, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co ²⁺ and Cu ²⁺) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1, 4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.

Original language	English (US)
Pages (from-to)	12387-12389
Number of pages	3
Journal	Inorganic chemistry
Volume	50
Issue number	24
DOIs	https://doi.org/10.1021/ic2020572
State	Published - Dec 19 2011

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title = "From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4- ",

abstract = "A 1D anionic polyoxometalate, [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4-, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co 2+ and Cu 2+) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1, 4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.",

author = "Shi, {Lian Xu} and Zhao, {Wen Feng} and Xuan Xu and Jing Tang and Wu, {Chuan De}",

year = "2011",

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doi = "10.1021/ic2020572",

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AU - Shi, Lian Xu

AU - Zhao, Wen Feng

AU - Xu, Xuan

AU - Tang, Jing

AU - Wu, Chuan De

PY - 2011/12/19

Y1 - 2011/12/19

N2 - A 1D anionic polyoxometalate, [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4-, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co 2+ and Cu 2+) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1, 4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.

AB - A 1D anionic polyoxometalate, [Mn 4(H 2O) 18WZnMn 2(H 2O) 2(ZnW 9O 34) 2] 4-, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co 2+ and Cu 2+) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1, 4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.

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From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn ₄(H ₂O) ₁₈WZnMn ₂(H ₂O) ₂(ZnW ₉O ₃₄) ₂] ^4-

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