Geminate ion-electron recombination kinetics in non-polar liquids by time-resolved fluorescence

Ann M. Brearley; Ramesh C. Patel; Daniel B. McDonald

doi:10.1016/0009-2614(87)80455-4

Geminate ion-electron recombination kinetics in non-polar liquids by time-resolved fluorescence

Ann M. Brearley, Ramesh C. Patel, Daniel B. McDonald

Biostatistics

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Abstract

The dynamics of geminate ion-electron recombination following laser photoionization of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) in non-polar solution were observed by time resolving the resulting delayed fluorescence. Geminate recombination was observed for TMPD excited by intense (3μJ) picosecond pulses of 305 nm light in low electron mobility solvents. Preliminary comparisons were made to theoretical models.

Original language	English (US)
Pages (from-to)	270-276
Number of pages	7
Journal	Chemical Physics Letters
Volume	140
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(87)80455-4
State	Published - Oct 2 1987

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Funding Information:
* Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Science, US-DOE under contract number W-31-109-ENG-38 Ii’ A value of G,,,= 5 is assumed.

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title = "Geminate ion-electron recombination kinetics in non-polar liquids by time-resolved fluorescence",

abstract = "The dynamics of geminate ion-electron recombination following laser photoionization of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) in non-polar solution were observed by time resolving the resulting delayed fluorescence. Geminate recombination was observed for TMPD excited by intense (3μJ) picosecond pulses of 305 nm light in low electron mobility solvents. Preliminary comparisons were made to theoretical models.",

author = "Brearley, {Ann M.} and Patel, {Ramesh C.} and McDonald, {Daniel B.}",

note = "Funding Information: * Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Science, US-DOE under contract number W-31-109-ENG-38 Ii{\textquoteright} A value of G,,,= 5 is assumed.",

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doi = "10.1016/0009-2614(87)80455-4",

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AU - Brearley, Ann M.

AU - Patel, Ramesh C.

AU - McDonald, Daniel B.

N1 - Funding Information: * Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Science, US-DOE under contract number W-31-109-ENG-38 Ii’ A value of G,,,= 5 is assumed.

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Y1 - 1987/10/2

N2 - The dynamics of geminate ion-electron recombination following laser photoionization of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) in non-polar solution were observed by time resolving the resulting delayed fluorescence. Geminate recombination was observed for TMPD excited by intense (3μJ) picosecond pulses of 305 nm light in low electron mobility solvents. Preliminary comparisons were made to theoretical models.

AB - The dynamics of geminate ion-electron recombination following laser photoionization of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) in non-polar solution were observed by time resolving the resulting delayed fluorescence. Geminate recombination was observed for TMPD excited by intense (3μJ) picosecond pulses of 305 nm light in low electron mobility solvents. Preliminary comparisons were made to theoretical models.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Geminate ion-electron recombination kinetics in non-polar liquids by time-resolved fluorescence

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