Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol)

S. Chandrasekhar; B. Saritha; V. Jagadeshwar; Ch Narsihmulu; Dolly Vijay; G. Dattatreya Sarma; B. Jagadeesh

doi:10.1016/j.tetlet.2006.02.104

Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol)

S. Chandrasekhar, B. Saritha, V. Jagadeshwar, Ch Narsihmulu, Dolly Vijay, G. Dattatreya Sarma, B. Jagadeesh

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Intramolecular hydrogen bonding facilitates nucleophilic addition of sulfones to Baylis-Hillman adducts in a single step to realize the substituted allyl sulfones. The reaction is performed in PEG (400 MW) as solvent, which allows easy solvent recycling.

Original language	English (US)
Pages (from-to)	2981-2984
Number of pages	4
Journal	Tetrahedron Letters
Volume	47
Issue number	17
DOIs	https://doi.org/10.1016/j.tetlet.2006.02.104
State	Published - Apr 24 2006
Externally published	Yes

Bibliographical note

Funding Information:
B.S., V.J., C.N., G.D.S. and D.V. thank CSIR and UGC, New Delhi. for financial assistance.

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title = "Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol)",

abstract = "Intramolecular hydrogen bonding facilitates nucleophilic addition of sulfones to Baylis-Hillman adducts in a single step to realize the substituted allyl sulfones. The reaction is performed in PEG (400 MW) as solvent, which allows easy solvent recycling.",

author = "S. Chandrasekhar and B. Saritha and V. Jagadeshwar and Ch Narsihmulu and Dolly Vijay and Sarma, {G. Dattatreya} and B. Jagadeesh",

note = "Funding Information: B.S., V.J., C.N., G.D.S. and D.V. thank CSIR and UGC, New Delhi. for financial assistance.",

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language = "English (US)",

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T1 - Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol)

AU - Chandrasekhar, S.

AU - Saritha, B.

AU - Jagadeshwar, V.

AU - Narsihmulu, Ch

AU - Vijay, Dolly

AU - Sarma, G. Dattatreya

AU - Jagadeesh, B.

N1 - Funding Information: B.S., V.J., C.N., G.D.S. and D.V. thank CSIR and UGC, New Delhi. for financial assistance.

PY - 2006/4/24

Y1 - 2006/4/24

N2 - Intramolecular hydrogen bonding facilitates nucleophilic addition of sulfones to Baylis-Hillman adducts in a single step to realize the substituted allyl sulfones. The reaction is performed in PEG (400 MW) as solvent, which allows easy solvent recycling.

AB - Intramolecular hydrogen bonding facilitates nucleophilic addition of sulfones to Baylis-Hillman adducts in a single step to realize the substituted allyl sulfones. The reaction is performed in PEG (400 MW) as solvent, which allows easy solvent recycling.

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M3 - Article

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 17

ER -

Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol)

Abstract

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