Incipient dynamics of swelling of gels

Hang Zhang, M. Carme Calderer

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

In this article, we analyze a model of the incipient dynamics of gel swelling and perform numerical simulations. The governing system consists of balance laws for a mixture of nonlinear elastic solid and solvent yielding effective equations for the gel. We discuss the multiscale nature of the problem and identify physically realistic regimes. The mixing mechanism is based on the Flory-Huggins energy. We consider the case that the dissipation mechanism is the solid-solvent friction force. This leads to a system of weakly dissipative nonlinear hyperbolic equations. After addressing the Cauchy problem, we propose physically realistic boundary conditions describing the motion of the swelling boundary. We study the linearized version of the free boundary problem. Numerical simulations of solutions are presented too.

Original languageEnglish (US)
Pages (from-to)1641-1664
Number of pages24
JournalSIAM Journal on Applied Mathematics
Volume68
Issue number6
DOIs
StatePublished - 2008

Keywords

  • Gel swelling
  • Hyperbolic free boundary problem
  • Polymer-solvent friction
  • Two-component mixture
  • Type II diffusion

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