Large Pressure Effects Caused by Internal Rotation in the s-cis-syn-Acrolein Stabilized Criegee Intermediate at Tropospheric Temperature and Pressure

Chemical Compounds

• Criegee Reaction 100%
• Internal Rotation 80%
• Unimolecular Reaction 73%
• Rate Constant 43%
• Pressure 38%
• Master Equation 37%
• Oxide 36%
• Transition State Theory 31%
• Cyclization Reaction 20%
• Coupled Cluster Theory 18%
• Ozonolysis 16%
• Rotamer 15%
• Wave Function 15%
• Vinyl Group 15%
• Isoprene 15%
• CCSD 14%
• Tunneling 13%
• Wave 12%

Engineering & Materials Science

• Pressure effects 89%
• Rate constants 82%
• Oxides 57%
• Cyclization 47%
• Wave functions 37%
• Temperature 26%
• Isoprene 21%
• Oxidants 17%
• Reaction rates 15%
• Atmospheric pressure 15%

Medicine & Life Sciences

• Acrolein 97%
• Oxides 80%
• Temperature 48%
• Pressure 43%
• Cyclization 40%
• isoprene 21%
• Atmospheric Pressure 18%
• Oryza 16%
• Oxidants 14%
• Kinetics 9%