LiClO4 electrolyte solvate structures

Wesley A. Henderson; Neil R. Brooks; William W. Brennessel; Victor G. Young

doi:10.1021/jp035836d

LiClO₄ electrolyte solvate structures

Wesley A. Henderson, Neil R. Brooks, William W. Brennessel, Victor G. Young

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

Two crystalline phases, (monoglyme)₂:LiClO₄ and (diglyme)₂:LiClO₄, have been isolated and characterized. The former consists of contact ion pairs in which the anions have bidentate coordination to the Li⁺ cations, while the latter consists of fully solvated Li⁺ cations in which the cations and anions do not directly interact. The two structures are useful as models for solvate structures in concentrated electrolyte mixtures. In particular, the phase behavior and solvate structures of solvent-salt mixtures are informative when coupled with vibrational spectroscopic analysis of ionic association behavior in solutions.

Original language	English (US)
Pages (from-to)	225-229
Number of pages	5
Journal	Journal of Physical Chemistry A
Volume	108
Issue number	1
DOIs	https://doi.org/10.1021/jp035836d
State	Published - Jan 8 2004

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abstract = "Two crystalline phases, (monoglyme)2:LiClO4 and (diglyme)2:LiClO4, have been isolated and characterized. The former consists of contact ion pairs in which the anions have bidentate coordination to the Li+ cations, while the latter consists of fully solvated Li+ cations in which the cations and anions do not directly interact. The two structures are useful as models for solvate structures in concentrated electrolyte mixtures. In particular, the phase behavior and solvate structures of solvent-salt mixtures are informative when coupled with vibrational spectroscopic analysis of ionic association behavior in solutions.",

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AU - Henderson, Wesley A.

AU - Brooks, Neil R.

AU - Brennessel, William W.

AU - Young, Victor G.

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N2 - Two crystalline phases, (monoglyme)2:LiClO4 and (diglyme)2:LiClO4, have been isolated and characterized. The former consists of contact ion pairs in which the anions have bidentate coordination to the Li+ cations, while the latter consists of fully solvated Li+ cations in which the cations and anions do not directly interact. The two structures are useful as models for solvate structures in concentrated electrolyte mixtures. In particular, the phase behavior and solvate structures of solvent-salt mixtures are informative when coupled with vibrational spectroscopic analysis of ionic association behavior in solutions.

AB - Two crystalline phases, (monoglyme)2:LiClO4 and (diglyme)2:LiClO4, have been isolated and characterized. The former consists of contact ion pairs in which the anions have bidentate coordination to the Li+ cations, while the latter consists of fully solvated Li+ cations in which the cations and anions do not directly interact. The two structures are useful as models for solvate structures in concentrated electrolyte mixtures. In particular, the phase behavior and solvate structures of solvent-salt mixtures are informative when coupled with vibrational spectroscopic analysis of ionic association behavior in solutions.

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LiClO₄ electrolyte solvate structures

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