Nitrogen-Nitrogen Double-Bond Scission of Azoarenes by Ru3(NAr)(CO)10. Struture and Catalytic Activity of H2Ru3(NAr)2(CO)8

Joanne A. Smieja; John E. Gozum; Wayne L. Gladfelter

doi:10.1021/om00141a040

Nitrogen-Nitrogen Double-Bond Scission of Azoarenes by Ru₃(NAr)(CO)₁₀. Struture and Catalytic Activity of H₂Ru₃(NAr)₂(CO)₈

Joanne A. Smieja, John E. Gozum, Wayne L. Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Azoarenes react with Ru₃(NArXCO)₁₀ giving Ru₃(NAr)(NAr‘XCO)₉ in high yields. These bis(imido) clusters react with H₂ to give H₂Ru₃(NAr)(NAr)(CO)₈, which can be used to catalyze the hydrogenation of olefins.

Original language	English (US)
Pages (from-to)	2154-2155
Number of pages	2
Journal	Organometallics
Volume	5
Issue number	10
DOIs	https://doi.org/10.1021/om00141a040
State	Published - Jan 1 1986

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AB - Azoarenes react with Ru3(NArXCO)10 giving Ru3(NAr)(NAr‘XCO)9 in high yields. These bis(imido) clusters react with H2 to give H2Ru3(NAr)(NAr)(CO)8, which can be used to catalyze the hydrogenation of olefins.

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Nitrogen-Nitrogen Double-Bond Scission of Azoarenes by Ru₃(NAr)(CO)₁₀. Struture and Catalytic Activity of H₂Ru₃(NAr)₂(CO)₈

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