Novel methodologies for the synthesis of functionalized lipophilic carboranes

Subash C. Jonnalagadda; Steven R. Verga; Parth D. Patel; A. V. Reddy; T. Srinivas; Patricia M Scott; Venkatram R Mereddy

doi:10.1002/aoc.1598

Novel methodologies for the synthesis of functionalized lipophilic carboranes

Subash C. Jonnalagadda, Steven R. Verga, Parth D. Patel, A. V. Reddy, T. Srinivas, Patricia M Scott, Venkatram R Mereddy

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9 Scopus citations

Abstract

Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C-C bond forming reactions, namely Baylis-Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization.

Original language	English (US)
Pages (from-to)	294-300
Number of pages	7
Journal	Applied Organometallic Chemistry
Volume	24
Issue number	4
DOIs	https://doi.org/10.1002/aoc.1598
State	Published - Apr 2010

Keywords

Baylis Hillman reaction
Carboranes
Cholesterol
Lipophilic carboranes
Low density lipoprotein

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abstract = "Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C-C bond forming reactions, namely Baylis-Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization.",

keywords = "Baylis Hillman reaction, Carboranes, Cholesterol, Lipophilic carboranes, Low density lipoprotein",

author = "Jonnalagadda, {Subash C.} and Verga, {Steven R.} and Patel, {Parth D.} and Reddy, {A. V.} and T. Srinivas and Scott, {Patricia M} and Mereddy, {Venkatram R}",

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AU - Verga, Steven R.

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AU - Reddy, A. V.

AU - Srinivas, T.

AU - Scott, Patricia M

AU - Mereddy, Venkatram R

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AB - Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C-C bond forming reactions, namely Baylis-Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization.

KW - Baylis Hillman reaction

KW - Carboranes

KW - Cholesterol

KW - Lipophilic carboranes

KW - Low density lipoprotein

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Novel methodologies for the synthesis of functionalized lipophilic carboranes

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Keywords

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