Observation of three intermolecular vibrational states of ArHF

M. A. Dvorak; S. W. Reeve; W. A. Burns; A. Grushow; K. R. Leopold

doi:10.1016/S0009-2614(91)85082-8

Observation of three intermolecular vibrational states of ArHF

M. A. Dvorak, S. W. Reeve, W. A. Burns, A. Grushow, K. R. Leopold

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

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Abstract

We report the observation of the (0, 1¹, 0), (0, 2⁰, 0), and (0, 0⁰, 2) states of the weakly bound complex ArHF by direct far infrared absorption spectroscopy in a jet. A simultaneous analysis of all observed rovibrational frequencies has been conducted, and spectroscopic constants sensitive to the global topology of the intermolecular potential energy surface are given.

Original language	English (US)
Pages (from-to)	399-402
Number of pages	4
Journal	Chemical Physics Letters
Volume	185
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(91)85082-8
State	Published - Oct 18 1991

Bibliographical note

Funding Information:
The support of the National Science Foundation (Grant No. CHE-8807895), the Donors of the Petroleum Research Fund, administered by the American Chemical Society, a Joseph H. DeFrees Grant of Research Corporation, the University of Minnesota, and the McKnight Foundation are gratefully acknowledged. We also thank Dr. Jeremy Hutson for providing us with valuable predictions, and Dr. David Nesbitt and Dr. Chris Lovejoy for helpful suggestions.

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title = "Observation of three intermolecular vibrational states of ArHF",

abstract = "We report the observation of the (0, 11, 0), (0, 20, 0), and (0, 00, 2) states of the weakly bound complex ArHF by direct far infrared absorption spectroscopy in a jet. A simultaneous analysis of all observed rovibrational frequencies has been conducted, and spectroscopic constants sensitive to the global topology of the intermolecular potential energy surface are given.",

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AU - Dvorak, M. A.

AU - Reeve, S. W.

AU - Burns, W. A.

AU - Grushow, A.

AU - Leopold, K. R.

N1 - Funding Information: The support of the National Science Foundation (Grant No. CHE-8807895), the Donors of the Petroleum Research Fund, administered by the American Chemical Society, a Joseph H. DeFrees Grant of Research Corporation, the University of Minnesota, and the McKnight Foundation are gratefully acknowledged. We also thank Dr. Jeremy Hutson for providing us with valuable predictions, and Dr. David Nesbitt and Dr. Chris Lovejoy for helpful suggestions.

PY - 1991/10/18

Y1 - 1991/10/18

N2 - We report the observation of the (0, 11, 0), (0, 20, 0), and (0, 00, 2) states of the weakly bound complex ArHF by direct far infrared absorption spectroscopy in a jet. A simultaneous analysis of all observed rovibrational frequencies has been conducted, and spectroscopic constants sensitive to the global topology of the intermolecular potential energy surface are given.

AB - We report the observation of the (0, 11, 0), (0, 20, 0), and (0, 00, 2) states of the weakly bound complex ArHF by direct far infrared absorption spectroscopy in a jet. A simultaneous analysis of all observed rovibrational frequencies has been conducted, and spectroscopic constants sensitive to the global topology of the intermolecular potential energy surface are given.

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Observation of three intermolecular vibrational states of ArHF

Abstract

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