Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production

Fenglin Liao; Xin Ping Wu; Jianwei Zheng; Meng Jung Li; Ziyan Zeng; Xinling Hong; Anna Kroner; Youzhu Yuan; Xue Qing Gong; Shik Chi Edman Tsang

doi:10.1039/c6cy01832g

Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production

Fenglin Liao, Xin Ping Wu, Jianwei Zheng, Meng Jung Li, Ziyan Zeng, Xinling Hong, Anna Kroner, Youzhu Yuan, Xue Qing Gong, Shik Chi Edman Tsang

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H₂ without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10^-1 s^-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.

Original language	English (US)
Pages (from-to)	7698-7702
Number of pages	5
Journal	Catalysis Science and Technology
Volume	6
Issue number	21
DOIs	https://doi.org/10.1039/c6cy01832g
State	Published - 2016

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© The Royal Society of Chemistry 2016.

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title = "Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production",

abstract = "It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10-1 s-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.",

author = "Fenglin Liao and Wu, {Xin Ping} and Jianwei Zheng and Li, {Meng Jung} and Ziyan Zeng and Xinling Hong and Anna Kroner and Youzhu Yuan and Gong, {Xue Qing} and Tsang, {Shik Chi Edman}",

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doi = "10.1039/c6cy01832g",

language = "English (US)",

volume = "6",

pages = "7698--7702",

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T1 - Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production

AU - Liao, Fenglin

AU - Wu, Xin Ping

AU - Zheng, Jianwei

AU - Li, Meng Jung

AU - Zeng, Ziyan

AU - Hong, Xinling

AU - Kroner, Anna

AU - Yuan, Youzhu

AU - Gong, Xue Qing

AU - Tsang, Shik Chi Edman

PY - 2016

Y1 - 2016

N2 - It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10-1 s-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.

AB - It is reported that well-dispersed core-shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe-ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10-1 s-1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.

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U2 - 10.1039/c6cy01832g

DO - 10.1039/c6cy01832g

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SN - 2044-4753

VL - 6

SP - 7698

EP - 7702

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 21

ER -

Pd@Zn core-shell nanoparticles of controllable shell thickness for catalytic methanol production

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