Photoluminescent Mn4 single-molecule magnet

Christopher C. Beedle; Casey Stephenson; Katie J. Heroux; Wolfgang Wernsdorfer; David N. Hendrickson

doi:10.1021/ic801485k

Photoluminescent Mn₄ single-molecule magnet

Christopher C. Beedle, Casey Stephenson, Katie J. Heroux, Wolfgang Wernsdorfer, David N. Hendrickson

Chemical Engineering and Materials Science

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59 Scopus citations

Abstract

The synthesis of [Mn₄(anca)₄(Hmdea) ₂(mdea)₂]·2CHCl₃ (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.

Original language	English (US)
Pages (from-to)	10798-10800
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	23
DOIs	https://doi.org/10.1021/ic801485k
State	Published - Dec 1 2008

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title = "Photoluminescent Mn4 single-molecule magnet",

abstract = "The synthesis of [Mn4(anca)4(Hmdea) 2(mdea)2]·2CHCl3 (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.",

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AU - Beedle, Christopher C.

AU - Stephenson, Casey

AU - Heroux, Katie J.

AU - Wernsdorfer, Wolfgang

AU - Hendrickson, David N.

PY - 2008/12/1

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Photoluminescent Mn₄ single-molecule magnet

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