Preparation and Reactivity of Mononuclear (η5-Cyclopentadienyl)cobalt Carbene Complexes

David W. Macomber; Robin D. Rogers

doi:10.1021/om00127a042

Preparation and Reactivity of Mononuclear (η⁵-Cyclopentadienyl)cobalt Carbene Complexes

David W. Macomber, Robin D. Rogers

Medicine - Geriatrics, Palliative and Primary Care (GPPC)

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Abstract

(η⁵-C₅H_s)Co(CO)₂ reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph₂S₂ to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

Original language	English (US)
Pages (from-to)	1485-1487
Number of pages	3
Journal	Organometallics
Volume	4
Issue number	8
DOIs	https://doi.org/10.1021/om00127a042
State	Published - Aug 1985

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title = "Preparation and Reactivity of Mononuclear (η5-Cyclopentadienyl)cobalt Carbene Complexes",

abstract = "(η5-C5Hs)Co(CO)2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph2S2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.",

author = "Macomber, {David W.} and Rogers, {Robin D.}",

year = "1985",

month = aug,

doi = "10.1021/om00127a042",

language = "English (US)",

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pages = "1485--1487",

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publisher = "American Chemical Society",

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T1 - Preparation and Reactivity of Mononuclear (η5-Cyclopentadienyl)cobalt Carbene Complexes

AU - Macomber, David W.

AU - Rogers, Robin D.

PY - 1985/8

Y1 - 1985/8

N2 - (η5-C5Hs)Co(CO)2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph2S2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

AB - (η5-C5Hs)Co(CO)2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph2S2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

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ER -

Preparation and Reactivity of Mononuclear (η⁵-Cyclopentadienyl)cobalt Carbene Complexes

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