Abstract
Hypervalent iodine (HVI) reagents have gained much attention as versatile oxidants because of their low toxicity, mild reactivity, easy handling, and availability. Despite their unique reactivity and other advantageous properties, stoichiometric HVI reagents are associated with the disadvantage of generating non-recyclable iodoarenes as waste/co-products. To overcome these drawbacks, the syntheses and utilization of various recyclable hypervalent iodine reagents have been established in recent years. This review summarizes the development of various recyclable non-polymeric, polymer-supported, ionic-liquid-supported, and metal organic framework (MOF)-hybridized HVI reagents. 1 Introduction 2 Polymer-Supported Hypervalent Iodine Reagents 2.1 Polymer-Supported Hypervalent Iodine(III) Reagents 2.2 Polymer-Supported Hypervalent Iodine(V) Reagents 3 Non-Polymeric Recyclable Hypervalent Iodine Reagents 3.1 Non-Polymeric Recyclable Hypervalent Iodine(III) Reagents 3.2 Recyclable Non-Polymeric Hypervalent Iodine(V) Reagents 3.3 Fluorous Hypervalent Iodine Reagents 4 Ionic-Liquid/Ion-Supported Hypervalent Iodine Reagents 5 Metal Organic Framework (MOF)-Hybridized Hypervalent Iodine Reagents 6 Conclusion.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2731-2748 |
| Number of pages | 18 |
| Journal | Synthesis (Germany) |
| Volume | 54 |
| Issue number | 12 |
| DOIs | |
| State | Published - Jun 15 2022 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2022 Georg Thieme Verlag. All rights reserved.
Keywords
- MOF hybrid
- hypervalent iodine
- ionic-liquid-supported
- non-polymeric
- polymer-supported
- recyclable reagents