Synthesis and structure of an organotitanoxane containing a tetrahedral Ti4O6 cage, [(η5-C5Me 5)Ti]4O6

L. M. Babcock; V. W. Day; W. G. Klemperer

doi:10.1039/C39870000858

Synthesis and structure of an organotitanoxane containing a tetrahedral Ti₄O₆ cage, [(η⁵-C₅Me ₅)Ti]₄O₆

L. M. Babcock, V. W. Day, W. G. Klemperer

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Abstract

Base hydrolysis of (η⁵-C₅Me₅)TiCl ₃ in toluene yields [(η⁵-C₅Me ₅)Ti]₄O₆ which, according to X-ray structural analysis, has an adamantane-like cage structure with a tetrahedral Ti ^IV₄O₆ core.

Original language	English (US)
Pages (from-to)	858-859
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39870000858
State	Published - 1987
Externally published	Yes

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title = "Synthesis and structure of an organotitanoxane containing a tetrahedral Ti4O6 cage, [(η5-C5Me 5)Ti]4O6",

abstract = "Base hydrolysis of (η5-C5Me5)TiCl 3 in toluene yields [(η5-C5Me 5)Ti]4O6 which, according to X-ray structural analysis, has an adamantane-like cage structure with a tetrahedral Ti IV4O6 core.",

author = "Babcock, {L. M.} and Day, {V. W.} and Klemperer, {W. G.}",

year = "1987",

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T1 - Synthesis and structure of an organotitanoxane containing a tetrahedral Ti4O6 cage, [(η5-C5Me 5)Ti]4O6

AU - Babcock, L. M.

AU - Day, V. W.

AU - Klemperer, W. G.

PY - 1987

Y1 - 1987

N2 - Base hydrolysis of (η5-C5Me5)TiCl 3 in toluene yields [(η5-C5Me 5)Ti]4O6 which, according to X-ray structural analysis, has an adamantane-like cage structure with a tetrahedral Ti IV4O6 core.

AB - Base hydrolysis of (η5-C5Me5)TiCl 3 in toluene yields [(η5-C5Me 5)Ti]4O6 which, according to X-ray structural analysis, has an adamantane-like cage structure with a tetrahedral Ti IV4O6 core.

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Synthesis and structure of an organotitanoxane containing a tetrahedral Ti₄O₆ cage, [(η⁵-C₅Me ₅)Ti]₄O₆

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