Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B12-catalyzed dehalogenation of chlorinated ethylenes

Autumn E. Rich; Angela D. DeGreeff; Kristopher McNeill

doi:10.1039/b109001a

Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B₁₂-catalyzed dehalogenation of chlorinated ethylenes

Autumn E. Rich, Angela D. DeGreeff, Kristopher McNeill

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

(Chlorovinyl)cobaloxime complexes, (dmgH)₂(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)₂Co(I) in the presence of pyridine.

Original language	English (US)
Pages (from-to)	234-235
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	3
DOIs	https://doi.org/10.1039/b109001a
State	Published - 2002

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abstract = "(Chlorovinyl)cobaloxime complexes, (dmgH)2(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)2Co(I) in the presence of pyridine.",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B12-catalyzed dehalogenation of chlorinated ethylenes

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AU - DeGreeff, Angela D.

AU - McNeill, Kristopher

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Y1 - 2002

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AB - (Chlorovinyl)cobaloxime complexes, (dmgH)2(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)2Co(I) in the presence of pyridine.

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Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B₁₂-catalyzed dehalogenation of chlorinated ethylenes

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