Synthesis of propionamide pyridine and pyridine N-oxide ligands

Iris Binyamin; Sylvie Pailloux; Benjamin P. Hay; Brian M. Rapko; Eileen N. Duesler; Robert T. Paine

doi:10.1002/jhet.5570440117

Synthesis of propionamide pyridine and pyridine N-oxide ligands

Iris Binyamin, Sylvie Pailloux, Benjamin P. Hay, Brian M. Rapko, Eileen N. Duesler, Robert T. Paine

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Abstract

(Chemical Equation Presented) A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with α-lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO₃)₃ has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO₃) ₃(H₂O).

Original language	English (US)
Pages (from-to)	99-103
Number of pages	5
Journal	Journal of Heterocyclic Chemistry
Volume	44
Issue number	1
DOIs	https://doi.org/10.1002/jhet.5570440117
State	Published - 2007
Externally published	Yes

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title = "Synthesis of propionamide pyridine and pyridine N-oxide ligands",

abstract = "(Chemical Equation Presented) A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with α-lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO3)3 has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO3) 3(H2O).",

author = "Iris Binyamin and Sylvie Pailloux and Hay, {Benjamin P.} and Rapko, {Brian M.} and Duesler, {Eileen N.} and Paine, {Robert T.}",

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T1 - Synthesis of propionamide pyridine and pyridine N-oxide ligands

AU - Binyamin, Iris

AU - Pailloux, Sylvie

AU - Hay, Benjamin P.

AU - Rapko, Brian M.

AU - Duesler, Eileen N.

AU - Paine, Robert T.

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with α-lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO3)3 has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO3) 3(H2O).

AB - (Chemical Equation Presented) A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with α-lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO3)3 has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO3) 3(H2O).

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Synthesis of propionamide pyridine and pyridine N-oxide ligands

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