Synthetic models of copper-nitrosyl species proposed as intermediates in biological denitrification

Debra J. Salmon; William B Tolman

doi:10.1007/430_2013_93

Synthetic models of copper-nitrosyl species proposed as intermediates in biological denitrification

Debra J. Salmon, William B Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Copper-containing nitrite reductase enzymes catalyze the reduction of nitrite to nitric oxide during denitrification, a key component of the global nitrogen cycle. Insights into the properties of proposed copper-nitrosyl intermediates have been obtained through studies of model complexes. Such complexes comprising both copper and nickel exhibit variable geometries and electronic structures that are influenced by the supporting ligands.

Original language	English (US)
Pages (from-to)	137-154
Number of pages	18
Journal	Structure and Bonding
Volume	154
DOIs	https://doi.org/10.1007/430_2013_93
State	Published - May 29 2014

Bibliographical note

Publisher Copyright:
© Springer-Verlag Berlin Heidelberg 2013.

Keywords

Copper
Model complex
Nitric oxide
Nitrite
Nitrite reductase

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abstract = "Copper-containing nitrite reductase enzymes catalyze the reduction of nitrite to nitric oxide during denitrification, a key component of the global nitrogen cycle. Insights into the properties of proposed copper-nitrosyl intermediates have been obtained through studies of model complexes. Such complexes comprising both copper and nickel exhibit variable geometries and electronic structures that are influenced by the supporting ligands.",

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AU - Tolman, William B

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AB - Copper-containing nitrite reductase enzymes catalyze the reduction of nitrite to nitric oxide during denitrification, a key component of the global nitrogen cycle. Insights into the properties of proposed copper-nitrosyl intermediates have been obtained through studies of model complexes. Such complexes comprising both copper and nickel exhibit variable geometries and electronic structures that are influenced by the supporting ligands.

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KW - Nitric oxide

KW - Nitrite

KW - Nitrite reductase

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Synthetic models of copper-nitrosyl species proposed as intermediates in biological denitrification

Abstract

Bibliographical note

Keywords

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