Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

Nyasha Kanganga; Kent R. Mann; Daron E. Janzen

doi:10.1107/S1600536808036726

Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

Nyasha Kanganga, Kent R. Mann, Daron E. Janzen

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, (C16H36N)2[Pt(C4N2S2)2], the Pt^II center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

Original language	English (US)
Pages (from-to)	m1552
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	12
DOIs	https://doi.org/10.1107/S1600536808036726
State	Published - 2008

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title = "Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)",

abstract = "In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.",

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AU - Janzen, Daron E.

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N2 - In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

AB - In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

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Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

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