TY - JOUR
T1 - The Formation and Chemistry of New Functionally Substituted n5-Cyclopentadienyl-Metal Compounds
T2 - Routes to New Vinyl Monomers
AU - Rausch, M. D.
AU - Hart, W. P.
AU - Macomber, D. W.
PY - 1981/1
Y1 - 1981/1
N2 - Reactions of cyclopentadienylsodium uith ethyl formate, methyl or ethyl acetate, or dimethyl carbonate in THF solution haue produced high yields of the functionally substituted organosodium compounds [C5-H4 C(0)R] Na+, where R = H, CH3, or OCH3. These organosodium reagents have proved to be valuable intermediates in the formation of functionally substituted cobaltocene, nickel-ocene, etc., sandwich complexes as yell as for other n5-cyclopentadienyl-metal systems such as (n5-C5H4CH)M(CO)2 (M = Co, Rh) and (T|5-C_H, CH0)W(CD),CH The latter aldehydes can be readily converted into corresponding acrylate and vinyl derivatives. The polymerization chemistry of these neu organometallic monomers has been initiated.
AB - Reactions of cyclopentadienylsodium uith ethyl formate, methyl or ethyl acetate, or dimethyl carbonate in THF solution haue produced high yields of the functionally substituted organosodium compounds [C5-H4 C(0)R] Na+, where R = H, CH3, or OCH3. These organosodium reagents have proved to be valuable intermediates in the formation of functionally substituted cobaltocene, nickel-ocene, etc., sandwich complexes as yell as for other n5-cyclopentadienyl-metal systems such as (n5-C5H4CH)M(CO)2 (M = Co, Rh) and (T|5-C_H, CH0)W(CD),CH The latter aldehydes can be readily converted into corresponding acrylate and vinyl derivatives. The polymerization chemistry of these neu organometallic monomers has been initiated.
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U2 - 10.1080/00222338108082049
DO - 10.1080/00222338108082049
M3 - Article
AN - SCOPUS:84914189503
SN - 0022-233X
VL - 16
SP - 243
EP - 250
JO - Journal of Macromolecular Science: Part A - Chemistry
JF - Journal of Macromolecular Science: Part A - Chemistry
IS - 1
ER -